In The Field

August 20, 2008

ACS Philadelphia 2008: Escaping the conference

I haven't spent much time outside the confines of the conference - apart from the sun-drenched stroll between the convention centre and another venue, the Sheraton, about a mile away.
So yesterday I thought, enough is enough. I went for a run over the Benjamin Franklin bridge with Neil Gussman, PR guy for the Chemical Heritage Foundation, and US army sergeant.

The run was amazing, the pedestrian bridge is much higher than the cars and the cars are much, much, much higher than the Delaware river. If you need to escape the city, you could do a lot worse than this towering piece of metal engineering.

Today I took another trip to CHF, to check out their new, and very impressive, gallery. It's still under construction, but the floor-to-ceiling interactive periodic table installment (made in part by he of the Periodic Table Table fame, Theo Gray) is already in place. It is awesome. Videos run for each element, and the whole thing cascades from the huge 2-storey ceiling to the floor on a massive array of TV screens.

The new galleries are also hosting a travelling art exhibit, molecules that matter. This is a collection of artists representations of 10 selected molecules that have influenced society in the past 100 years. Apparently the choice of molecules upset some staunch organic chemists. I can't see why. You should pop over and see if you're getting cabin fever in the conference.

Posted by Katharine Sanderson at 10:41 PM |

ACS Philadelphia 2008: When will cheap solar power become reality?

The answer to the question posed above isn't clear. I went to a session about plastic devices that could be used as solar cells instead of expensive silicon, hoping to hear a breathrough was nigh. Sadly i was wrong. Advances in plastics that can capture light over a useful wavelength, that can separate the charge into electrons and holes, that can carry that charge and finally, do something useful with it are being made. But slowly.

Talking in the session was Fred Wudl, who was first to develop fullerene/polymer systems as photovoltaic cells. It seems that the system he hit upon first up has been hard to beat, at least according to Mats Andersson, from Chalmers University of Technology, Gothenburg, who was also speaking in the session.

Percentage power conversion efficiencies remain low. The very best results are around 5%, and these tend to be from a single, meticulously prepared sample - a long way from a manfacturable, large scale printing porcess that is hoped for. To be really viable, a system that is 10% efficient is needed, or a slightly less efficient, but very cheap plastic material that can be made to cover a large area. But still, despite lots of tinkering with the polymers in the systems, the best that Andersson presented was 2.8% efficiency. Manpreet Kaur, from Virginia polytechnic presented a system with an efficiency of 1%.

The systems rely on the electron-transporting porperties of a polymer, and the hole (absence of electron) transporting properties of the fullerene groups. The main way to change these systems is altering the polymer groups.

The field is gaining strength, however. One company, Konarka, is claiming that it will have a flexible, efficient, solar cell plastic available by the end of the year. We shall have to wait and see.

The session certainly generated interest, but i can't help think that the efficiencies are going to remain low for a while yet. Perhaps next year, if Konarka has delivered, academics will have joined them in finding a more efficient system.

Posted by Katharine Sanderson at 10:11 PM |

ACS Philadelphia 2008: on the presidential campaign trail

At the general poster session the other night I was delighted to see the two candidates campaigning for the job everyone is talking about. No, not McCain and Obama, but the two candidates for the president-elect of the ACS. As the biggest scientific society in the world, this is a big job.

As I approached one of the candidates, Josef Michl, I noticed he was chattering to Bob Grubbs (see earlier post). Michl was very keen on sustainabilty. And this is a broad recurring theme of this meeting. Chemists realise the opportunites they have to help the planet. Of course, chemistry is the underpinning science to the techologies that are being investigated to replace fossil fuels. I can only imagine that in future this theme is going to engulf these meetings even more.

The other presidential-elect candidate had a very firm handshake and free colour-changing pencils. Another Joseph, from Purdue, Joseph Francisco told me about his plans to unite retired chemists and young, keen postdocs to create an ACS-centred bank of expertise. is focus was much more on the business side of chemistry, and in particular small businesses.

Two very differnent candidates with very different agendas. It will be interesting to see who wins. At the moment I wouldn't like to call it, but the trend towards sustainability gives me the feeling that Michl might just steal it.

Posted by Katharine Sanderson at 03:34 PM |

August 19, 2008

ACS Philadelphia 2008: Viruses make batteries

I wrote a story yesterday about a clever way to make tiny batteries using a rubber stamp and a virus. It was actually from a paper that came out in PNAS, but one of the authors, Paula Hammond is here at the meeting. She is working with Angela Belcher on some very cool viruses.

The paper outlines a simple way to build up a polyelectrolyte system, and coat a virus onto it, then let cobalt oxide nanoparticles grow on that. Stamp all this cobalt-side down on to a platinum strip, add a thin piece of lithium to the other side and hey-presto! A teeny tiny battery.

In my discussions with others about the work, it seems that people have been playing around with viruses for a while now, but we should start to see a lot more practical applications coming out of this tinkering in the next few years.

Posted by Katharine Sanderson at 06:18 PM |

ACS Philadelphia 2008: Posters...

Last night was the poster session. It was late, I was jet-lagged, tired and emotional, but I dutifully showed up, if only to get my free beer. As ever this was a really well-attended event. It's impossible to see everything so I decided to pick some of my favourite titles for you to muse over. They show the amazing breadth of this meeting, and some of them actually make chemistry sound, well, really interesting.**

Impact of thermal and nonthermal processing techologies on quality of apple cider (one close to my heart)

Lanthanide pyrone and pyridone complexes for the treatment of bone density disorders

Reinvigorating the chemistry curriculum with Fourier-Transform Nuclear Magnetic Resonance (FT-NMR) spectroscopy

Measurement of the contact angle of a water droplet on a flat surface

Heavy metal accumulation by common garden plants: A chemical and spectroscopic approach

** i'm not saying that chemistry isn't interesting, by the way. I love chemistry, but sometimes it is hard to persuade others not involved in the field

Posted by Katharine Sanderson at 03:42 PM |

August 18, 2008

ACS Philadelphia 2008: Bad luck strikes - twice

Some people have all the bad luck. I was recommended to go this morning to a session on self-replication. Sounds cool, i thought. I bet it will be busy...

But I was very wrong. Where was everyone? The recommendation turned out to be right, and I really enjoyed Douglas Philp's talks about self-replicating systems, but the room must have had about 15 people in it. I didn't get it, so I asked Philp how come he had failed to pull in the punters. "I was up against Bob Grubbs," he said.

Ah, it all becomes clear. That's bad luck I said. Grubbs is a Nobel prize-winning chemist from Caltech who is a giant in the catalysis world. He even has his own catalyst.

Poor Doug, I thought. Still, better luck for his next talk this afternoon. Nope, it seems the Philp brand of chemistry will fail to reach the masses once more. This afternoon he is up against Barry Sharpless, also a Noble prize-winning chemist, from Scripps, who has more than one eponymous reaction.

Ouch.

The message to Doug Philp, and anyone else landed with these unfortunate timetable clashes is clear: you're going to have to get a reaction or a catalyst named ofter you. Or you're going to have to win the Nobel prize in chemistry. Preferrably both.

Better luck next year, eh?

Posted by Katharine Sanderson at 09:16 PM |

ACS Philadelphia 2008: Big talk

A few weeks ago I wrote a news story about some work done by Dan Nocera at MIT. He's managed to make a very simple catalyst that can generate oxygen directly from water - so helping those people trying to mimic photosynthesis and save the world's energy crisis.

At the time Nocera wasn't sure what the mechanism was for the formation of the cobalt catalyst. In today's talk he confirmed what he had thought then - that the cobalt gets oxidised all the way to its +4 oxidation state. He was also very confident in the technology he is developing. "I guarantee in under five years you'll see this," he said. Companies are coming out of the woodwork, he says, to develop a functioning, practical system.

Other big claims he made were that in a system based on his catalyst cuold produce enough fuel to run a typical house for a day in just two and a half hours. This is big talk, Dan, I look forward to it becoming reality.

Posted by Katharine Sanderson at 06:33 PM |

ACS Philadelphia 2008: Trees eat pollution

I had a slight deviation from the ACS yesterday while i finished up writing a story about trees that can absorb organic nitrates and turn them into amino acids. But seeing as in that single sentence I spotted at least four chemistry-relate words I thought this would be a good place to write about the research.

I shan't go into loads of details, because then you might not go and read the story (and i can't believe anyone would miss out on the chance to do that), but the news here is thus: trees, well known to gobble up inorganic nitrogen compounds, can also take up - and use, more importantly - organic nitrates that are the porducts of NOx emissions and the volatile organic compounds that trees spew out.

It's not yet clear whether this mechanism might actually help to alleviate NOx pollution, and at the same time increase photosynthesis thereby locking up more carbon. If that were the case that would be a very good news story indeed. It looks more likely that this effect is dependent on local conditions. And as the author Paul Shepson told me, even if the mechanism does help clean up the atmopshere a bit, the better solution is to stop the emissions in the first place.

Posted by Katharine Sanderson at 06:14 PM |

August 17, 2008

ACS Philadelphia 2008: And another thing...

A number of other Nature publishing group staff are here, and are also blogging over at the chemistry blog, The Sceptical Chymist.

Between us we have more of a chance to cover a wide range of chemistry - hopefully something for everyone's taste. I recommend a read.

Posted by Katharine Sanderson at 10:41 PM |

ACS Philadelphia 2008: Board

The meeting is in full swing, and here in the city of brotherly love, beshorted chemists can be spotted all over the place. Quite a sight for the uninitiated, i can assure you.

I wandered into the ACS board meeting this morning, which also includes bigwigs from other international chemical societies today. It was an open meeting, I didn't gatecrash. I got there in time to hear a discussion about what the ACS can do to be more sustainable.

Continue reading "ACS Philadelphia 2008: Board" »

Posted by Katharine Sanderson at 08:11 PM |

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