« Reactions - Dongyuan Zhao | Main | Oooh! Aaaah! »

NChem Research Highlights: layering liquids, double metallocenes and fixing fingerprints

Time for another dose of Research Highlights - we scour the literature so you don't have to...

First up, would you expect ionic liquids to separate into layers of anions and cations on surfaces? At first glance, you'd probably think they'd mix it around to balance the charge - but not if the surface is charged, as is the case.

Next we have some 'double metallocenes' - rather than just one Cp (or indeed Cp*) ring above and below the metal, these have two fused Cp* rings sandwiching two metals. In the 250-word article, I didn't have space to go into the full story of the magnetic, electronic and redox properties investigated, so you'll have to go over to JACS for the details.

Serendipity...not just a good name for a cat or a posh word for luck. Where would chemistry be without it? In this case, without a method for 'fixing' fingerprints. While trying to make sulfur nitride polymers Paul Kelly and colleagues noticed that the precursor, disulfur dinitride, was so reactive that it was even reacting with the fingerprints on the glassware...and you can imagine the rest!

Neil


Neil Withers (Associate Editor, Nature Chemistry)

TrackBack

TrackBack URL for this entry:
http://blogs.nature.com/cgi-bin/mt/mt-tb.cgi/6525

Post a comment

Comments will be reviewed by the editors before being published. You can be as critical or controversial as you like, but please don't get personal or offensive. We strongly encourage you to use your real, full name. Email addresses are required: this is in case we need to discuss your comment with you privately, or notify you in case we decide not publish your comment. Email addresses will not be made public on the blog.


Please enter the numbers you see below - this helps us to cut down on spam. If you are having trouble with this system, you can instead e-mail a comment to 'thescepticalchymist at boston dot nature dot com '.

Subscribe

Subscribe to this blog's feeds:

[What is this?]

Recent Comments

Out of 972 total comments,
the most recent were:
Powered by
Movable Type 3.2